Browsing by Author "Baba A."

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A brief overview on geothermal scaling
(General Directorate of Mineral Research and Exploration (MTA), 2023) Isik T.; Baba A.; Chandrasekharam D.; Demir, M.M.
Hot spring waters are rich in terms of minerals. Since there are dramatic changes in thermodynamic parameters in geothermal power plants, such as a decrease in temperature and pressure, severe precipitation occurs throughout the system components in an uncontrolled manner. There are three main chemistries in deposits: carbonates (mainly calcium carbonates), silicates (metal silicates), and sulphides (antimony sulphide-stibnite). Energy harvesting is remarkably reduced out of the insulating nature of the deposit. Various actions need to be taken to mitigate this undesirable issue of scaling in geothermal systems. Geothermal systems are in fact quite complex, and the composition of brine and, accordingly, the chemistry of the deposit are not identical. Therefore, each system should be studied individually, and a tailor-made remedy should be developed. In this overview, the types of deposits in terms of chemistry and the actions (pH modification or antiscalant dosing) that should be taken to reduce scaling are mentioned, and potential chemistries of antiscalants are given. © 2023 General Directorate of Mineral Research and Exploration (MTA). All rights reserved.
Characterization of Sb scaling and fluids in saline geothermal power plants: A case study for Germencik Region (Büyük Menderes Graben, Turkey)
(Elsevier Ltd, 2021) Tonkul S.; Baba A.; Demir M.M.; Regenspurg, S.
Turkey is located on the seismically active Alpine-Himalayan belt. Although tectonic activity causes seismicity in the Anatolian plate, it also constitutes an important geothermal energy resource. Today, geothermal energy production is heavily concentrated in Turkey's Western Anatolia region. Graben systems in this region are very suitable for geothermal resources. The Büyük Menderes Graben (BMG) is an area of complex geology with active tectonics and high geothermal potential power. Germencik (Aydın) is located in the BMG, where the geothermal waters include mainly Na-Cl-HCO3 water types. This study examined the stibnite scaling formed in the preheater system of the Germencik Geothermal Field (GGF). The formation of the stibnite scaling on the preheater system dramatically reduces the energy harvesting of the GGF. Considering the stibnite scaling in the surface equipment, the optimum reinjection temperature was determined as 95 °C to prevent stibnite scaling in the GGF. © 2021 Elsevier Ltd
Geological and hydrogeochemical properties of geothermal systems in the southeastern region of Turkey
(Elsevier Ltd, 2019) Baba A.; Şaroğlu F.; Akkuş I.; Özel N.; Yeşilnacar M.İ.; Nalbantçılar M.T.; Demir M.M.; Gökçen G.; Arslan Ş.; Dursun N.; Uzelli T.; Yazdani, H.
The Anatolia region is one of the most seismically active regions in the world. It has a considerably high level of geothermal energy potential thanks to its geological and tectonic settings. The Southeastern Anatolia Region (GAP) is located in the south of Bitlis-Zagros Suture Zone (BZSZ) which is in the Arabian foreland. During the neotectonic period, the folded structures have been developed under the influence of tectonic compression from the Upper Miocene in the GAP Region where it is closely related to active tectonics. These tectonic activities produce more geothermal resources. Few studies have been carried out in this region for geothermal energy. Limited portions of the geothermal resources have been used both for thermal tourism and greenhouses in the GAP region. The aim of this study is to determine geological, tectonic and hydrogeochemical properties of a geothermal system in the GAP Region. The result indicates that the surface temperatures of geothermal fluids are from 20 to 84.5 °C A large number of abandoned oil wells, whose temperature reaches 140 °C, are found in the region. Also, hydrogeochemical results show that deep circulated geothermal fluids are enriched with Na-Cl and shallow geothermal system fluids have Na−HCO3 and Ca-SO4 characters because of cold water mixing and water-rock interaction. Cold waters are generally of Ca-Mg−HCO3 and Ca−HCO3 type. Cation geothermometers were used for determining reservoir temperature of the geothermal resources in the region. The results show that the reservoir temperature of these geothermal resources ranges from 50 °C to 200 °C. The isotope data (oxygen-18, deuterium and tritium) suggests that geothermal fluid is formed by local recharge and deep circulation. © 2018 Elsevier Ltd
Hydrogeology and hydrogeochemistry of the geothermal systems and its direct use application: Balçova-Narlıdere geothermal system, İzmir, Turkey
(Elsevier Ltd, 2022) Baba A.; Sözbilir H.; Sayık T.; Arslan S.; Uzelli T.; Tonkul S.; Demir, M.M.
The Balçova-Narlıdere geothermal system, located in western Turkey, is an extensional domain type geothermal play. Geological, hydrogeological, and geothermal studies have been done in the Balçova-Narlıdere geothermal field since 1960. As a result of these studies, production and research wells were drilled in the area by both the public and private sectors. Of the 37 wells drilled in the Balçova-Narlıdere geothermal field, 26 were drilled by İzmir Geothermal Energy Company Inc. (16 productions, 4 re-injection, 4 gradientst, 2 unused) and 11 by the İzmir Governorship Investment Monitoring and Coordination Department and companies in the private sectors. There are two reservoirs, one shallow and one deep, in the geothermal field. Well depths are less than 200 m in the shallow reservoir. The deep production wells have depths ranging from 400 to 1,100 m and reservoir temperatures reaching 140 °C. The electrical conductivity (EC) values in the shallow production wells range from 1,200 to 1,500 µS/cm. EC values in the deep production wells vary from 1,871 to 2,025 µS/cm, and all geothermal fluids in the field are mineral-rich waters. In the İzmir geothermal district heating system, the newest technologies are used, and operational costs are very low. İzmir Geothermal Energy Company Inc. has been operating since 1996 and has reached 38,460 residences. The current capacity of the system is approximately 160 MWt. Cooling systems continue to spread in Turkey, focusing on electric air conditioning systems and geothermal heating systems, but both economic and applicability problems have slowed the expansion of cooling systems. However, İzmir Geothermal Energy Company Inc. began operating its first geothermal cooling application in Balçova in 2018, cooling 1,900 m2 of the indoor area by lithium bromide absorption and 90/85 °C geothermal temperature regime by supplying 6/9 °C clean cold water to the coolers in the buildings. These results show that the extensional domain type geothermal system in the Balçova-Narlıdere region is suitable for both heating and cooling applications. © 2022
The injection of CO2 to hypersaline geothermal brine: A case study for Tuzla region
(Elsevier Ltd, 2019) Topcu G.; Koç G.A.; Baba A.; Demir, M.M.
Scaling is a serious issue for geothermal power plants since it remarkably decreases the harvesting of energy. The reduction of pH by organic acids whose structure is close to CO2 for instance formic acid has been an effective solution for the minimization of scaling. Herein, the effect of CO2 injection on the formation of scaling particularly metal-silicates was investigated for the model case of Tuzla Geothermal Field (TGF) located in the northwest of Turkey. CO2 has an acidic character in aqueous systems because it leads to the formation of carbonic acid. The injection of 20.6 m3/s CO2 (approximately 88 ppm) to hypersaline brine of TGF is a promising green approach for both mitigation of scaling by reducing pH from 7.2 to 6.2 at the well-head and the minimization of potential corrosion compared to the use of formic acid (55 ppm). © 2019 Elsevier Ltd
Investigation of lithium sorption efficiency using swcnt functionalized electrospun fiber mats from the hypersaline geothermal brine
(Trans Tech Publications Ltd, 2018) Çelik A.; Topçu G.; Isik T.; Baba A.; Horzum N.; Demir, M.M.
Geothermal mining from brines becomes increasingly important with the increasing demand for rare earth elements in various engineering applications. Geothermal fluids contain valuable minerals and metals such as silica, zinc, lithium, and other materials that can be processed to recover these products. Solution mining by nature is challenging because of variable composition as well as the concentration of the interfering ions, particularly calcium and magnesium, and the presence of interfering ions increases the recovery costs requiring additional steps. The aim of this study is the fabrication of single-walled carbon nanotube functionalized electrospun chitosan, poly(methyl methacrylate) (PMMA), and polyacrylonitrile (PAN) fiber mats. Effect of polymer type, dilution factor, and surface modification on the sorption of lithium (Li+) ions was investigated. The maximum sorption performance was obtained with SWCNT functionalized PAN (15 wt%) fiber mats and they have sorption percentage as 55% at diluted (1/100) brine samples. © 2018 Trans Tech Publications, Switzerland.